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唐亞文教授課題組在NEW JOURNAL OF CHEMISTRY發(fā)表研究論文

時間：2021-04-09 13:19:02學(xué)院：化學(xué)與材料科學(xué)學(xué)院學(xué)校：南京師范大學(xué)
Facile fabrication of hierarchical Rh2Ir alloy nanodendrites with excellent HER performance in a broad pH range
Liu, QC (Liu, Qicheng)[ 1 ] ; Fan, C (Fan, Chuang)[ 1 ] ; Zhou, XY (Zhou, Xinyi)[ 1 ] ; Liu, JQ (Liu, Jiaqi)[ 1 ] ; Jiang, S (Jiang, Shuang)[ 1 ] ; Wang, SY (Wang, Siyuan)[ 1 ] ; Wang, XJ (Wang, Xiaojun)[ 2 ] *; Tang, YW (Tang, Yawen)[ 1 ]*（唐亞文）

[ 1 ]? Nanjing Normal Univ, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Peoples R China
[ 2 ]? Nanjing Normal Univ, Sch Life Sci, Nanjing 210023, Peoples R China


NEW JOURNAL OF CHEMISTRY 2020,44, 21021-21025


It is a difficult and long-term task to develop highly active and stable electrocatalysts to realize efficient hydrogen evolution reaction (HER) in electrochemical water splitting. Herein, we report a facile oil-bath method to fabricate hierarchical Rh2Ir alloy nanodendrites (Rh2Ir NDs) with excellent HER performance in a broad pH range. Due to the unique branched nanostructure and rational Rh2Ir metal proportion, the developed Rh2Ir NDs exhibit superior activity and enhanced stability towards HER in a broad range of pH conditions. To deliver a current density of 10 mA cm(-2) in 1 M HClO4 and 1 M KOH, Rh2Ir NDs require overpotentials of only 12 and 9 mV, respectively. This work not only offers a high-performance electrocatalyst for electrochemical water splitting but also provides a new perspective towards the rational synthesis of hierarchical noble-metal nanodendrites.



文章鏈接：
https://pubs.rsc.org/en/content/articlelanding/2020/NJ/D0NJ04512H#!divAbstract




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